Home|Journals|Articles by Year

Directory for Medical Articles
 

Original Article

ECB. 2013; 2(5): 255-258


SYNTHESES AND SPECTRAL CHARACTERIZATION OF SOME NOVEL MACROCYCLIC COMPLEXES OF OXOVANADIUM(IV) WITH 1,1’-OXALYLDIIMIDAZOLE

Ashok Kumar Yadava, Hardeo Singh Yadav, Devendra Pratap Rao.


Abstract

A new series of five complexes of oxovanadium(IV) with the general formula [VO(mac)]SO4 (where mac = tetraazamacrocyclic ligands
derived by condensation of 1,1’-oxalyldiimidazole with 1,2-diaminopropane and their reactions with β-diketones) have been prepared using
oxometal ion as kinetic template. The prepared complexes have been characterized on the basis of electrical conductance, molecular
weight, magnetic moment, elemental analyses, infrared, e.s.r. and electronic spectral data. The probable coordination number of central
metal is five (distorted square-pyramid).

Key words: oxovanadium(IV), amines, kinetic template, macrocyclic complexes






Full-text options


Share this Article



Online Article Submission
• ejmanager.com
• ojshosting.net







Do you want to use OJS for your journal ?
work with an experienced partner
www.OJSHosting.net

eJManager.com
Review(er)s Central
About BiblioMed
License Information
Terms & Conditions
Privacy Policy
Contact Us

The articles in Bibliomed are open access articles licensed under the terms of the Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License (https://creativecommons.org/licenses/by-nc-sa/4.0/) which permits unrestricted, non-commercial use, distribution and reproduction in any medium, provided the work is properly cited.