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Original Article

ECB. 2014; 3(9): 857-859


COMPLEX FORMATION OF 1,4-DIAZABICYCLO[2.2.2]OCTANE WITH COPPER(II) TETRASULFOPHTHALOCYANINE IN AQUEOUS SOLUTION

Alena Voronina, Natalya Litova, Ilya Kuzmin, Mihail Razumov, Artur Vashurin, Maxim Shepelev, Svetlana Pukhovskaya.




Abstract

The self-association in the formation of copper tetrasulfophthalocyanine complex and 1,4-diazabicyclo[2.2.2.]octane (DABCO) in aqueous
solution are reported. Formation of phthalocyanine π-π dimers and a CuPc-DABCO complex could be confirmed, however, formation of
sandwich-type dimers could not be detected.

Key words: water-soluble phthalocyanine, solution, complex formation, DABCO, spectroscopy






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