Home|Journals|Articles by Year|Audio Abstracts RSS - TOC
 

Original Article

ECB. 2014; 3(5): 482-484


STRUCTURE OF N-HYDROXY-4-PHENYLBUT-3-EN-2-IMINE

Preetika Sharma, S. Samshuddin, B. Narayana, Rajni Kant.




Abstract

The title compound, N-hydroxy-4-phenylbut-3-en-2-imine [C10H11NO], was synthesized by reacting benzylideneacetone with
hydroxylamine hydrochloride in the presence of base. The structure of the compound was characterized by single crystal XRD data. It
crystallizes in the orthorhombic space group Pbc21 with unit-cell parameters: a= 5.591(6)Å, b=22.019(3)Å, c = 14.742(2) Å, β = 90.0º, Z =
4. The crystal structure has been elucidated by Direct methods and refined to a final R-value of 0.056 for 1535 observed reflections. In
the crystal molecules are linked by two N-H...N intermolecular H-bonds forming dimer. Molecules in the unit cell are packed together to
form well defined layers.

Key words: oximes; intermolecular hydrogen bond; crystal structure; direct methods; N-hydroxy-4-phenylbut-3-en-2-imine






Full-text options


Share this Article



Online Article Submission
• ejmanager.com
• ojshosting.net




eJManager.com
Review(er)s Central
JournalList
About BiblioMed
License Information
Terms & Conditions
Privacy Policy
Contact Us

The articles in Bibliomed are open access articles licensed under the terms of the Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License (https://creativecommons.org/licenses/by-nc-sa/4.0/) which permits unrestricted, non-commercial use, distribution and reproduction in any medium, provided the work is properly cited.