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Research Article

ECB. 2019; 8(11): 376-382


TETRASUBSTITUTED (4-CHLOROPHENOXY)- AND (2,4,5-TRICHLOROPHENOXY)PHTHALOCYANINE METAL(II)COMPLEXES AND THEIR SULPHONATED DERIVATIVES: SYNTHESIS AND PROPERTIES

Dmitry Erzunov, Tatiana Tikhomirova, Dmitry Filippov, Vladimir Maizlish, Igor Abramov, Arthur Vashurin.




Abstract

By template condensation of 4-(4-chlorophenoxy)- and 4-(2,4,5-trichlorophenoxy)phthalonitriles with cobalt(II), copper(II) and zinc(II) acetates, the corresponding metal(II) phthalocyaninates were synthesized, and some of their sulfonic acid derivatives were also isolated after sulphonation reactions. The spectroscopic characteristics and some physicochemical properties of the synthesized compounds were also given.

Key words: 4-Nitrophthalonitrile; phthalocyanine; synthesis; sulfonation; electronic absorption spectra.






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